A combined theoretical treatment of T(1)-->S(0) intersystem crossing and intramolecular vibrational redistribution in thiophosgene |
| |
Authors: | Rashev Svetoslav Moule David C |
| |
Affiliation: | Institute of Solid State Physics, Bulgarian Academy of Sciences, Tsarigradsko Chaussee 72, 1784 Sofia, Bulgaria. rasheev@issp.bas.bg |
| |
Abstract: | We combine our two recent theoretical approaches for electronic relaxation T(1)-->S(0) and vibrational relaxation processes in thiophosgene (SCCl(2)) to provide a more detailed picture of the intersystem crossing (ISC) and phosphorescence from the first triplet T(1). Our analysis shows that ISC is not a true irreversible decay and should lead to violent phosphorescence quantum beats that could be observed experimentally. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|