Syntheses of [Rh(NH3)5Cl][MCl6] (M = Re, Os, Ir) and Investigation of Their Thermolysis Products. Crystal Structure of [Rh(NH3)5Cl][OsCl6] |
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| Authors: | S. A. Gromilov S. V. Korenev I. A. Baidina I. V. Korolkov K. V. Yusenko |
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| Affiliation: | (1) Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk;(2) Novosibirsk State University, Russia |
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| Abstract: | Binary complex salts [Rh(NH3)5Cl][MCl6], where M = Re, Os, Ir, have been synthesized and characterized. X-ray diffraction analysis indicated that the salts are isostructural. According to X-ray phase analysis, the products of their thermolysis in hydrogen are monophase stoichiometric nonequilibrium solid solutions Rh0.5M0.5 (M = Re, Os, Ir). The molecular and crystal structures of [Rh(NH3)5Cl][OsCl6] were determined in an X-ray structural analysis. |
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