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硫化镉晶体结构形态对乙醇光催化脱氢活性的影响
引用本文:方智敏 庄启星. 硫化镉晶体结构形态对乙醇光催化脱氢活性的影响[J]. 高等学校化学学报, 1992, 13(8): 1131-1133
作者姓名:方智敏 庄启星
作者单位:厦门大学化学系, 厦门, 361005
摘    要:有关醇类水溶液光催化贮能脱氢反应研究大多集中在提高半导体TiO2和CdS表面修饰组分的光催化活性[1~3]及考察TiO2半导体晶体结构与光催化性能的关系上[4,5],CdS半导体晶体结构形态对光催化性能的影响尚未见报道.本文在这方面进行了一些有益的研究.

关 键 词:光催化  脱氢  晶体结构形态  
收稿时间:1991-08-12

Effect of the Crystal Structural Morphology of CdS on the Photocatalytic Dehydrogenation Activity of Ethanol
FANG Zhi-Min,ZHUANG Qi-Xing. Effect of the Crystal Structural Morphology of CdS on the Photocatalytic Dehydrogenation Activity of Ethanol[J]. Chemical Research In Chinese Universities, 1992, 13(8): 1131-1133
Authors:FANG Zhi-Min  ZHUANG Qi-Xing
Affiliation:Department of Chemistry, Xiamen University, Xiamen, 361005
Abstract:The photocatalytic dehydrogenation of aqueous solution of ethanol on two types of CdS supports with different crystal structures modified by either the chemically deposited Pd or mechanically mixed Pt was investigated.The crystal structural morphology of the CdS semiconductor powders was determined by TEM and XRD.The relationship between the CdS crystal structural morphology and the dehydrogenation behavior of the catalysts was illustrated and the fact that the photocatalytic dehydrogenation of aqueous solution of ethanol is quite sensitive to the crystal structural morphology of catalyst support was confirmed.
Keywords:Photocatalysis  Dehydrogenation  Crystal structural morphology
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