Institut für Organische Chemie der Universität, Auf der Morgenstelle 18, D-7400 Tübingen F.R.G.
Laboratoire de Synthèse Asymétrique, Université Paris-Sud, F-91405 Orsay France
Abstract:
Molybdenum(VI)(oxo-diperoxo) complexes bearing bidentate ligands with hydroxy and carbonyl functions show asymmetric induction in the stoichiometric epoxidation of simple prochiral olefins. The influence of the ligand and alkene structure on the enantiomeric excess of the oxiranes has been investigated. The addition of chiral diols to the molybdenum(VI)(oxo-diperoxo) reagents gives high enantiomeric excesses probably because of an efficient kinetic resolution of the oxiranes formed.