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| Syntheses and Characterizations of Two New Organic-inorganic Hybrids Based on Heteropolymolybdates and Piperidine Molecules | |
| 作者姓名： | 周端文 张宏 杨振芳 |
| 作者单位： | Department of Pharmacy and Applied Chemistry Jilin Institute of Chemical Technology，Department of Chemistry Northeast Normal University，Department of Chemistry Northeast Normal University，Jilin 132073 China，Changchun 130024 China，Changchun 130024 China |
| 基金项目： | This project was financially supported by the National Science Foundation of China (No. 20371012) |
| 摘 要： | 1 INTRODUCTION The rational design and synthesis of organic-inor- ganic hybrid materials have recently attracted an increasing interest not only from a structural point of view, but also due to their potential applications in different areas such as catalysis, medicine, sorption, electrical conductivity, magnetism and photoche- mistry1~8]. It should be noted that polyoxometalates (POMs)9~11], known as their wide applications in many interdisciplinary fields, are an outstanding class o… |
| 关 键 词： | 合成 表征 有机-无机混合物 杂聚钼酸盐 哌啶分子 热水方法 |
Syntheses and Characterizations of Two New Organic-inorganic Hybrids Based on Heteropolymolybdates and Piperidine Molecules |
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| ZHOU Duan-Wen,ZHANG Hong,YANG Zhen-Fang.Syntheses and Characterizations of Two New Organic-inorganic Hybrids Based on Heteropolymolybdates and Piperidine Molecules[J].Chinese Journal of Structural Chemistry,2006,25(3):312-320. | |
| Authors: | ZHOU Duan-Wen ZHANG Hong YANG Zhen-Fang |
| Institution: | 1. Department of Pharmacy and Applied Chemistry, Jilin Institute of Chemical Technology, Jilin 132073, China 2. Department of Chemistry, Northeast Normal University, Changchun 130024, China 3. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
| Abstract: | Two new organic-inorganic compounds (CH2)5NH2]3PMo12O40]·3(CH2)5NH] 1 and (CH2)5NH2]6P2Mo18O62]·5H2O 2 have been synthesized using conventional and hydrothermal methods, respectively, and characterized by elemental analyses, IR, TG and single-crystal X-ray diffraction. X-ray analyses show that in these compounds heteropolymolybdates PMo12O40]3- and P2Mo18O62]6- are reserved their Keggin or Dawson structures and linked to piperidine through electrostatic and hydrogen-bonding interactions. |
| Keywords: | organic-inorganic hybrids heteropolymolybdates piperidine molecules |
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