Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex |
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| Authors: | Moxham Gemma L Brayshaw Simon K Weller Andrew S |
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| Institution: | Department of Chemistry, University of Bath, Bath, UK. |
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| Abstract: | Reaction of Ir(PPh(3))(2)(COD)]BAr(F)(4)] with H(2) in dichloroethane solution results in Ir(PPh(3))(2)(H)(2)(ClCH(2)CH(2)Cl)]BAr(F)(4)], which has been fully characterised by X-ray crystallography, NMR spectroscopy and ESI-MS. Its activity towards alkene hydrogenation has been compared with analogous CH(2)Cl(2) complexes. |
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