Ti-amide catalyzed synthesis of cyclic guanidines from di-/triamines and carbodiimides |
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| Authors: | Shen Hao Wang Yang Xie Zuowei |
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| Affiliation: | Department of Chemistry and State Key Laboratory on Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, N.T., Hong Kong, China. |
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| Abstract: | A titanacarborane monoamide catalyzed, one-step synthesis of mono/bicyclic guanidines from commercially available di/triamines and carbodiimides is reported. The reaction mechanism is also proposed. |
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