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Novel Azo‐Dyes‐Modified Isatin Derivatives: Synthesis,UV/VIS Spectroscopic,and Electrochemical Study
Authors:Lenar I. Musin  Ilnur T. Abdullin  Alexander E. Vandyukov  Dmitry G. Yakhvarov  Ruzal G. Zinnatullin  Vladimir F. Mironov  Andrei V. Bogdanov
Affiliation:1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation;2. Kazan Federal University, Kazan, Russian Federation;3. +7‐843‐2727374+7‐843‐2732253
Abstract:A high‐yield and simple synthesis of certain aminomethylisatins bearing dye fragments via the Mannich reaction of isatin with amino‐containing azobenzenes was reported. It was found that the absence of electron‐donating groups in azo‐dye molecule prevents aminomethylation of isatin. The effect of the incorporation of an isatin moiety with an azobenzene dye in one molecule on its absorption and electrochemical behavior was studied using UV spectroscopy and cyclic voltammetry.
Keywords:Isatin  Azo‐dyes  Isoindigo  UV/VIS spectroscopy  Cyclic voltammetry
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