| 具有二维纳米孔径结构Ni3(H2O)6(TMA)3-(TMA)23-·2H2O(TMA=均苯三甲酸)的合成、晶体结构和磁性研究 |
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| 引用本文： | 陈伟,谭小娜,黎玉梅,郑吉民,车云霞. 具有二维纳米孔径结构Ni3(H2O)6(TMA)3-(TMA)23-·2H2O(TMA=均苯三甲酸)的合成、晶体结构和磁性研究[J]. 无机化学学报, 2005, 21(12): 1901-1904 |
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| 作者姓名： | 陈伟 谭小娜 黎玉梅 郑吉民 车云霞 |
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| 作者单位： | 天津南开大学化学系,天津,300071 |
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| 基金项目： | 国家自然科学基金资助项目(No.50242001)，南开大学本科生创新基金资助项目。 |
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| 摘 要： | A novel coordination polymer nickel 1,3,5-benzenetricarboxylate (TMA) Ni3(H2O)6(TMA)3-(TMA)23-·2H2O with two-dimensional porous structure was synthesized and characterized. It crystallizes in the hexagonal system, space group P6522, with a=1.665 2(10) nm, c=2.045 4(11) nm, V=4.912(5) nm3, Z=6, Dc=1.916 g·cm-3, μ(Mo Kα)=0.181 8 mm-1, F(000)=2 892. The final R1=0.066 4, wR2=0.175 6 for 2 710 observed reflections [I>2σ(I)] out of 2 904 unique reflections . This coordination polymer reveals not only two-dimensional porous structure but also particular magnetic properties. CCDC: 274177.
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| 关 键 词： | 合成； 晶体结构； 均三苯甲酸； 磁性 |
| 文章编号： | 1001-4861(2005)12-1901-04 |
| 收稿时间： | 2004-07-15 |
| 修稿时间： | 2005-08-24 |
Synthesis, Crystal Structure and Magnetic Properties of Ni3(H2O)6(TMA)3-(TMA)3 3-· 2H2O with Two-dimensional Aperture Strucutre |
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| CHEN Wei,TAN Xiao-N,LI Yu-Mei,ZHENG Ji-Min and CHE Yun-Xia. Synthesis, Crystal Structure and Magnetic Properties of Ni3(H2O)6(TMA)3-(TMA)3 3-· 2H2O with Two-dimensional Aperture Strucutre[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(12): 1901-1904 |
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| Authors: | CHEN Wei TAN Xiao-N LI Yu-Mei ZHENG Ji-Min CHE Yun-Xia |
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| Affiliation: | Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
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| Abstract: | |
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| Keywords: | synthesis crystal structure TMA magnetic properties |
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