| Novel Photoinduced Electron Transfer Reaction of N-methylphenothiazine in Carbon Tetrachloride |
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| 作者姓名： | Xia GUO Li YANG Long Min WU You Cheng LIU and Zhong Li LIU |
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| 作者单位： | National Laboratory of Applied Organic Chemistry，Lanzhou University，Lanzhou，Gansu 730000 |
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| 摘 要： | PhenothiazinederivativeshaveattractedmuchinterestforalongtimeduetotheirdiversechemicalandbioIogicalproperties,aswellasmedicalaPplicationsl.Theradicalcationofphenothiazinesisbelievedtobeinvolvedinthebiotransformationofphenothiazinedrugs2andnumerousstudieshavethusfocusedonthegenerationandreactionsofphenothiazineradicalcations3-6.WereporthereinanovelphotochemicalreactionofN-methylphenothiazineincarbontetrachloridewhichcoupIestwoparentmoleculeswitheliminationofonemethylgroup(Schemel).Resultsandd…
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Novel Photoinduced Electron Transfer Reaction of N-methylphenothiazine in Carbon Tetrachloride |
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| Xia GUO, Li YANG, Long Min WU, You Cheng LIU and Zhong Li LIU.Novel Photoinduced Electron Transfer Reaction of N-methylphenothiazine in Carbon Tetrachloride[J].Chinese Chemical Letters,1998(3). |
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| Authors: | Xia GUO Li YANG Long Min WU You Cheng LIU and Zhong Li LIU |
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| Abstract: | U.V. irradiation of N-methylphenothiazine 1 in carbon tetrachloride produced 3-(phenothiazin-N-yl- carbonyl ) -N-methylphenothiazine 2 together with the radical cation salt 1 CCl4- and methyl chloride, presumably via a photoinduced electron transfer mechanism. |
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| Keywords: | methylphenothiazine photoinduced reaction carbon tetrachloride |
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