Palladium-catalyzed allylation of imines with allyl alcohols |
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| Authors: | Shimizu Masamichi Kimura Masanari Watanabe Toshiya Tamaru Yoshinao |
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| Institution: | Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan. |
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| Abstract: | A catalytic system, Pd(OAc)2 (10 mol %)-P(n-Bu)3 (20 mol %)-Et3B (360 mol %), promotes allylic alcohols to undergo the allylation of anisidine-imines of aromatic and aliphatic aldehydes and furnishes homoallylamines in good to moderate yields. The reaction shows unique stereoselectivity, giving anti-isomers selectively. reaction: see text] |
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