A double-layered photoanode made of ZnO/TiO2 composite nanoflowers and TiO2 nanorods for high efficiency dye-sensitized solar cells |
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Authors: | Xiaobo Chen Qianwen Du Wen Yang Weiwei Liu Zhongzheng Miao Peizhi Yang |
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Affiliation: | 1.School of New Energy and Electronic Engineering,Yancheng Teachers University,Yancheng,People’s Republic of China;2.Key Laboratory of Education Ministry for Advance Technique and Preparation of Renewable Energy Materials, Institute of Solar Energy,Yunnan Normal University,Kunming,People’s Republic of China |
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Abstract: | We present a simple sol-gel hydrothermal process for the fabrication of a double-layered structure composed of a TiO2 nanorod overlayer and TiO2 nanoparticle-embedded ZnO nanoflower (ZNFs@TNPs-TNRs) underlayer. The ZNFs@TNPs-TNRs was used as a photoanode in dye-sensitized solar cells (DSSCs) and their photovoltaic performance was analyzed. The ZNFs@TNPs-TNRs can enhance the adsorption of N719 dyes, charge transport, and light scattering. The cell performances can be maximized by optimizing thickness ratio and total thickness of the double-layered photoanode, and the preliminary results demonstrate that a promising power conversion efficiency (PCE) of 8.01% is determined on the DSSC with ZNFs@TNPs-TNRs anode, yielding a 28.9% enhancement in the PCE in comparison to pristine TiO2–P25 nanoparticle-based DSSC. |
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