Metastable one-dimensional AgCl(1)-(x)I(x) solid-solution wurzite "tunnel" crystals formed within single-walled carbon nanotubes |
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| Authors: | Sloan Jeremy Terrones Mauricio Nufer Stefan Friedrichs Steffi Bailey Sam R Woo Hee-Gweon Rühle Manfred Hutchison John L Green Malcolm L H |
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| Institution: | Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, United Kingdom. |
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| Abstract: | High-resolution transmission electron microscopy and spatially resolved electron loss spectroscopy have revealed that a eutectic mixture of AgCl and AgI crystallizes within single walled carbon nanotubes (SWNTs) as metastable AgCl(1-)(x)I(x) 1D solid solution crystals. The incorporated halide crystals form wurzite "tunnel" structures with locally varying Cl:I ratios and reduced Ag coordination. |
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