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Effect of the inclusion of a cyclic fragment in the chromophore on the properties of a spiropyran-merocyanine system
Authors:M A Gal'bershtam  A P Sidorov  N M Przhiyalgovskaya  Yu P Strokach  V A Barachevskii  I V Manakova  N N Suvorov
Institution:(1) Scientific-Research Institute of Organic Intermediates and Dyes, 103787 Moscow;(2) D. Mendeleev Moscow Institute of Chemical Technology, 125047 Moscow
Abstract:The corresponding merocyanines, which do not display a tendency to form spiropyran structures, are formed in the condensation of 1,3,3-trimethyl-2-methyleneindoline with 5-methyl-2-furoylacetaldehyde, 2-formylcyclohexanone, or 2-formyl-1-tetralone. Spiran compounds in which the spiropyran—merocyanine equilibrium is shifted markedly to favor the closed form are formed when 4a,9-dimethyl-2,3,4,4a-tetrahydrocarbazone — the cyclic analog of the Fischer base — is used in the reaction with salicylaldehydes and benzoylacetaldehydes.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1205–1210, September, 1982.
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