A cyclic hexamer of silver trifluoroacetate supported by four triphenylphosphine sulfide template molecules |
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Authors: | Djordjevic Bratislav Schuster Oliver Schmidbaur Hubert |
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Institution: | Department Chemie, Technische Universit?t München, Lichtenbergstrasse 4, 85747 Garching, Germany. |
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Abstract: | Crystallization of silver trifluoroacetate from chloroform solutions containing triphenylphosphine sulfide affords a trigonal and a monoclinic form of a 6:4 complex {CF3C(O)OAg]6(Ph3PS)4} of C2 symmetry with different amounts of chloroform in the crystals. With the Ph3PS components as template molecules, the CF3C(O)OAg units are assembled to form a 6-membered metallacycle codetermined by metallophilic bonding and enclosed by a 24-membered ring AgOCO]6. A complex of the type LAgOC(O)CF3]2, with L representing the isocyanide ligand pTolSO2CH2NC, has been shown to have a conventional bicyclic structure with three-coordinate silver atoms engaged in transannular metallophilic interactions. |
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