| A Layered Vanadium Oxide with Cobalt（Ⅱ） Coordination Complex： Hydrothermal Synthesis and Crystal Structure of （py）5Co2（H2O）3[V4O12] |
| |
| 引用本文： | 王艳艳,代纪香,张千峰. A Layered Vanadium Oxide with Cobalt（Ⅱ） Coordination Complex： Hydrothermal Synthesis and Crystal Structure of （py）5Co2（H2O）3[V4O12][J]. 结构化学, 2009, 28(10): 1187-1189 |
| |
| 作者姓名： | 王艳艳 代纪香 张千峰 |
| |
| 作者单位： | Institute;Molecular;Engineering;Applied;Chemistry;Anhui;University;Technology; |
| |
| 基金项目： | supported by the Science and Technological Fund of Anhui Province for Outstanding Youth and the Program for New Century Excellent Talents in University (06046100 and NCET-06-0556) |
| |
| 摘 要： | A novel layered mixed metal vanadium-cobadt complex, （py）5Co2（H2O）3[V4O12] 1 （py = pyridine）, was hydro（solvo）thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in orthorhombic, space group Pca21 with a = 17.473（4）, b = 11.447（2）, c = 17.509（4）A^°, V = 5005.3（7）A^°3, Z = 4, Mr = 3502.1（12）, Z = 4, Dc = 1.827 g/cm^3,μ（MoKα） = 2.023 mm^-1, F（000） = 1928, S = 1.020, the final R = 0.0400 and wR= 0.1063 for 6035 observed reflections with I 〉 2σ（I） and 460 variables. Complex 1 consists of tetrahedral VO4 groups to form the large layers which are alternately bonded by two cobalt complex species Co（py）2（H2O）2 and Co（py）3（H2O）.
|
| 关 键 词： | 钴(Ⅱ)配合物 水热合成 晶体 氧化钒 单晶X射线衍射 层状 结构 正交晶系 |
A Layered Vanadium Oxide with Cobalt(Ⅱ) Coordination Complex:Hydrothermal Synthesis and Crystal Structure of (py) 5Co2(H2O)3[V4O12] |
| |
| WANG Yan-Yan,DAI Ji-Xiang,ZHANG Qian-Feng. A Layered Vanadium Oxide with Cobalt(Ⅱ) Coordination Complex:Hydrothermal Synthesis and Crystal Structure of (py) 5Co2(H2O)3[V4O12][J]. Chinese Journal of Structural Chemistry, 2009, 28(10): 1187-1189 |
| |
| Authors: | WANG Yan-Yan DAI Ji-Xiang ZHANG Qian-Feng |
| |
| Abstract: | A novel layered mixed metal vanadium-cobadt complex,(py) _5Co_2(H_2O)_3[V_4O_(12)] 1(py=pyridine),was hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in orthorhombic,space group Pca2_1 withα=17.473(4)(A),b=11.447(2),c= 17.509(4)(A),V=5005.3(7)(A)~3,Z=4,Mr=3502.1(12),Z=4,Dc=1.827 g/cm~3,μ(MoKα)=2.023 mm~(-1),F(000)=1928,S=1.020,the final R=0.0400 and wR-0.1063 for 6035 observed reflections with Ⅰ> 2σ(Ⅰ) and 460 variables. Complex 1 consists of tetrahedral VO_4groups to form the large layers which are alternately bonded by two cobalt complex species Co(py)_2(H_2O)_2and Co(py)_3(H_2O). |
| |
| Keywords: | polyoxometalate layered complex hydrothermal synthesis crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
