| 麦草伏甲酯对对映体的高效液相色谱分离 |
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| 引用本文： | 侯士聪,王敏,乔振,郭红超,史雪岩,周志强. 麦草伏甲酯对对映体的高效液相色谱分离[J]. 应用化学, 2003, 20(5): 505-507 |
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| 作者姓名： | 侯士聪 王敏 乔振 郭红超 史雪岩 周志强 |
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| 作者单位： | 中国农业大学 |
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| 摘 要： | 手性分离;麦草伏甲酯对对映体的高效液相色谱分离
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| 关 键 词： | 手性分离 麦草伏甲酯对对映体的高效液相色谱分离 |
| 文章编号： | 1000-0518(2003)05-0505-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2002-07-09 |
Direct Resolution of Flamprop-methyl Enantiomers by HPLC |
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| HOU Shi Cong,WANG Min,QIAO Zhen,GUO Hong Chao,SHI Xue Yan,ZHOU Zhi Qiang. Direct Resolution of Flamprop-methyl Enantiomers by HPLC[J]. Chinese Journal of Applied Chemistry, 2003, 20(5): 505-507 |
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| Authors: | HOU Shi Cong WANG Min QIAO Zhen GUO Hong Chao SHI Xue Yan ZHOU Zhi Qiang |
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| Affiliation: | HOU Shi Cong,WANG Min,QIAO Zhen,GUO Hong Chao,SHI Xue Yan,ZHOU Zhi Qiang * |
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| Abstract: | Cellulose tris(3,5 dimethylphenylcarbamate)(CDMPC) was prepared and coated onto an aminopropylated mesopore spherical silica gel. The final product was used as the chiral stationary phase in high performance liquid chromatography for enantioseparation. The enantiomers of Flamprop methyl were resoluted directly on this kind of chiral stationary phase(CSP) with a mixture of hexane and 2 propanol as a mobile phase. The effects of concentration of 2 propanol in the mobile phase on the retention and resolution were investigated. The structural features of the solutes that influence chiral separation and the chiral recognition mechanism and the eluted sequence were discussed. |
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| Keywords: | high performance liquid chromatography Flamprop methyl enantiomer resolution |
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