| 前线聚合研究及应用进展(上) |
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| 引用本文： | 崔艳艳,杨建文,曾兆华,陈用烈.前线聚合研究及应用进展(上)[J].高分子通报,2006(7):53-58. |
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| 作者姓名： | 崔艳艳 杨建文 曾兆华 陈用烈 |
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| 作者单位： | 中山大学化学与化工学院,广州,510275 |
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| 摘 要： | 前线聚合(Frontal Polymerization,FP)是一种以自身反应热为推动力,通过反应区域连续移动,最终实现整体聚合转化的聚合反应模式。本文综述介绍了前线聚合的定义、反应机理、基本形成条件及主要特点。
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| 关 键 词： | 前线聚合 自由基聚合 放热反应 热对流 瑞利-泰勒效应 |
Advances on the Investigation and Application of Frontal Polymerization-Part A |
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| CUI Yan-yan,YANG Jian-wen,ZENG Zhao-hua,CHEN Yong-lie.Advances on the Investigation and Application of Frontal Polymerization-Part A[J].Polymer Bulletin,2006(7):53-58. |
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| Authors: | CUI Yan-yan YANG Jian-wen ZENG Zhao-hua CHEN Yong-lie |
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| Abstract: | Frontal polymerization is a mode of converting monomer into polymer via a localized exothermic reaction zone that propagates through the coupling of thermal diffusion and the Arrhenius reaction kinetics of an polymerization.The definition,reaction mechanism and prominent characteristics of the frontal polymerization are reviewed in this article.The conditions for the existence of free-radical thermal frontal polymerization are considered. |
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| Keywords: | Frontal polymerization Free radical polymerization Exothermic reaction Convection Rayleigh-Taylor effect |
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