Stability of 3d-element cyclotetraphosphates in water |
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| Authors: | G. S. Kuanysheva K. U. Dzhamansarieva G. Zh. Sdikova |
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| Affiliation: | (1) Al-Farabi State University of Kazakhstan, pr. al-Farabi 71, Almaty, 050038, Kazakhstan;(2) Satpaev State Technical University of Kazakhstan, ul. Satpaeva 23, Almaty, 050013, Kazakhstan |
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| Abstract: | The hydrolysis kinetics of the anion in 3d-element cyclotetraphosphates is considered. The thermodynamic functions of formation (Δ f H 0, Δ f G 0, and Δ f ? at 0 ) of the cyclotetraphosphates are calculated using the ion increment method. A linear correlation is established between and log K Δ f ? at 0 for these compounds. |
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