Synthesis and luminescent properties of Cu(II), Zn(II) polymeric complexes with electron- and hole-transporting groups |
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Authors: | Aihong He Hualiang Huang Yu Zhou Yan He Hailiang Zhang |
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Institution: | Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, PR China |
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Abstract: | A novel ligand 3,6-bis(1,10-phenathroline-5,6-d] imidazole-2-yl)carbazole (Bpic) containing hole- and electron-transporting groups was firstly designed. Its polymeric complexes of Bpic with Cu(∥), Zn(∥) were successfully synthesized. The UV-vis absorption, fluorescence spectra and thermal properties of these complexes were investigated. At room temperature, complexes 2, 3 emit blue luminescence from 445 to 485 nm in DMSO solution, and emit green/yellow and orange luminescence from 523 to 585 nm in solid state. In comparison with the free ligand, the polymeric complexes exhibit a bathochromic shift. It can be assigned to the extended π-conjugation of the complexes. |
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Keywords: | Carbazole 1 10-phenanthroline Polymeric complexes Luminescence |
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