Dissociation Constant of Acetic Acid in (N,N-Dimethylformamide + Water) Mixtures at the Temperature 298.15 K |
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Authors: | Yuliya A Fadeeva Lyubov P Safonova |
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Institution: | (1) Department of Chemical Metrology, Kharkov V.N. Karazin National University, Svoboda Sq. 4, 61077 Kharkov, Ukraine |
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Abstract: | In the present work the thermodynamic dissociation constants of acetic acid were determined in (N,N-dimethylformamide (DMF) + water)
mixtures over the DMF mole fraction range from 0 to 0.65 at the temperature 298.15 K by the potentiometric titration method.
The dissociation constant in pure DMF was obtained by extrapolation and comparative calculation methods. The dependence of
the acetic acid dissociation constant on the mixed solvent composition was fitted with linear multiple regression of the solvatochromic
parameters of (DMF + water) mixtures at every studied composition. |
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