A coupling reaction between tetrahydrofuran and olefins by Rh-catalyzed/Lewis acid-promoted C-H activation |
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| Authors: | Ke Cao Shu-Yu Zhang Yong-Qiang Tu Yuan-Jiang Pan |
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| Affiliation: | a State Key Laboratory of Applied Organic Chemistry and Department of Chemistry, Lanzhou University, Lanzhou 730000, PR China
b Department of Chemistry, Zhejiang University, Hangzhou 310027, PR China |
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| Abstract: | A novel coupling reaction between tetrahydrofuran and olefins is discovered, in which the consecutive C-C and C-Cl bond-forming process takes place via Rh-catalyzed/lewis acid-promoted C-H activation. This reaction could be developed into a straightforward and effective method for rapid access to 2-(2-chloro-2-arylethyl)-tetrahydrofuran compounds. |
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| Keywords: | THF C-H activation Coupling reaction Lewis acid |
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