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A novel one-pot synthesis of 3-carbomethoxy-4-arylfuran-2-(5H)-ones from ketones using [hydroxy(tosyloxy)iodo]benzene |
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| Authors: | Nandkishor N. Karade Sumeet V. Gampawar Jeevan M. Kondre Sandeep V. Shinde |
| Affiliation: | School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, Maharashtra, India |
| Abstract: | A novel one-pot procedure for the synthesis of 3-carbomethoxy-4-aryl furan-2-(5H)-ones is reported via α-tosyloxylation of enolisable ketones with [hydroxy(tosyloxy)iodo]benzene, followed by treatment with potassium monomethyl malonate and K2CO3. |
| Keywords: | Hypervalent iodine γ-Lactone Potassium monomethyl malonate Enolisable ketone |
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