1,3-Dipolar cycloaddition reactions of benzo[b]thiophene 1,1-dioxide with azomethine ylides |
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Authors: | Nela Malatesti |
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Affiliation: | Department of Chemistry, University of Hull, Cottingham Road, Hull HU6 7RX, UK |
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Abstract: | New pyrrolo derivatives of benzo[b]thiophene 1,1-dioxide have been synthesised via 1,3-dipolar cycloaddition reactions. Reaction of benzo[b]thiophene 1,1-dioxide with stabilised azomethine ylides gave products in low yield but high stereoselectivity whereas reaction with non-stabilised azomethine ylides gave high overall yields but low stereoselectivity. |
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Keywords: | 1,3-Dipolar cycloaddition reactions Benzo[b]thiophene 1,1-dioxide Azomethine ylides Regio- and stereoselectivity |
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