Stereoselective total synthesis of (+)-aspicilin |
| |
Authors: | Sadagopan Raghavan T Sreekanth |
| |
Institution: | Organic Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| |
Abstract: | A stereoselective synthesis of (+)-aspicilin is described. Regio- and stereoselective functionalization by intramolecular participation of the sulfinyl group, ene reaction, and macrolactonization by Wadsworth-Emmons reaction employing Masamune-Roush protocol are the key steps of the route. |
| |
Keywords: | Aspicilin Sulfinyl group Ene reaction Macrolactonization |
本文献已被 ScienceDirect 等数据库收录! |