Synthesis and ESR behaviors of nitroxide monoradical based on calix[4]arene |
| |
| Authors: | Xiaojun Hu Haijun Yang Yanghe Luo |
| |
| Affiliation: | Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, PR China |
| |
| Abstract: | A novel paramagnetic calix[4]arene 6 with an N-O monoradical on the upper rim was synthesized and studied by ESR spectroscopy. Its ESR behaviors were mainly induced by its intrinsic conformational flexibility. The effects of varying temperature and complexation of silver ions on its ESR behaviors were also investigated. |
| |
| Keywords: | Calix[4]arene Nitroxide radical Conformation ESR |
| 本文献已被 ScienceDirect 等数据库收录！ |
