On the use of (TMS)3CH as novel tin-free radical reducing agent |
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| Authors: | V Tamara Perchyonok |
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| Institution: | ISOF, Consiglio Nazionale delle Ricerche, Via P. Gobetti 101, 40129 Bologna, Italy |
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| Abstract: | (TMS)3CH is an efficient free radical reducing agent. Debromination, deiodation, dechlorination as well as decarboxylation of Barton and Kim esters can proceed smoothly using this tin-free reducing agent. Rate constants for hydrogen atom abstraction from TMS3CH by primary radicals were also determined. |
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