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Syntheses of heliannuols G and H; structure revision of the natural products
Authors:Sachie Morimoto  Masahiro Yoshida
Affiliation:a Graduate School of Pharmaceutical Sciences, The University of Tokushima, 1-78-1 Sho-machi, Tokushima 770-8505, Japan
b Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasugakoen, Kasuga 816-8580, Japan
Abstract:The structures of the natural heliannuols G and H were established by the enantiocontrolled syntheses of the dihydrobenzofurans predicted for the natural products employing the palladium-mediated cyclization and cross metathesis as the key steps.
Keywords:Sesquiterpene   Heliannuol   Dihydrobenzofuran   Palladium-mediated cyclization   Cross metathesis
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