Multidentate aminophenol ligands prepared with Mannich condensations |
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Authors: | Christine S. Higham Janet L. Shaw Christopher J. Ziegler |
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Affiliation: | a Department of Chemistry, College of the Holy Cross, Worcester, MA 01610, USA b Department of Chemistry, University of Akron, Akron, OH 44325, USA |
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Abstract: | Mannich condensations were used to prepare a series of multidentate aminophenol compounds from ethylenediamine, various amounts of paraformaldehyde and 2,4-disubstituted phenols. One of these diaminotetraphenol compounds was reacted with Zn(OAc)2·2H2O and the resulting solid state structure of the pentacoordinated Zn(II) compound was determined by single crystal X-ray diffraction analysis. |
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Keywords: | Mannich condensation Zn(II) Benzoxazine |
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