Synthesis of tunable phosphinite-pyridine ligands and their applications in asymmetric hydrogenation |
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| Authors: | Qi-Bin Liu |
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| Institution: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, Liaoning 116023, PR China |
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| Abstract: | A new class of modular conformationally rigid N,P ligands is conveniently synthesized from readily available starting material. Iridium complexes with these ligands have demonstrated excellent enantioselectivity (up to 99% ee) in the asymmetric hydrogenation of aryl alkenes. |
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