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Novel thermal iminocyclopropene rearrangements: regioselectivity in the synthesis of pyrroles
Authors:Hiroyasu Sato
Affiliation:Ohu University, The School of Pharmaceutical Sciences, Department of Synthetic Organic Chemistry, 31-1 Misumido, Tomitamachi, Koriyama, Fukushima 963-8611, Japan
Abstract:A novel and readily available method for synthesis of pyrroles possessing substituents with various functional groups has been developed, by means of thermal iminocyclopropene rearrangements. It will provide a novel and readily available access to pyrroles under mild reaction conditions with simple procedures. The regioselectivity in this iminocyclopropene rearrangement was disclosed.
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