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Pentafluorophenyltrifluorosilane in the silicon Mannich reaction |
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| Authors: | Alexander D Dilman Vladimir V Gorokhov Pavel A Belyakov Marina I Struchkova Vladimir A Tartakovsky |
| Institution: | ND Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation |
| Abstract: | The synthesis of α-C6F5-substituted amines by a three-component coupling reaction of C6F5SiF3, aromatic aldehydes, and N-trimethylsilylamines has been elaborated. The optimized conditions include performing the reaction in dimethylformamide in the presence of stoichiometric amounts of lithium acetate. |
| Keywords: | Fluorinated silanes Hypervalent silicon Mannich reaction |
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