A simple synthesis of 2-arylbenzothiazoles and its application to palladium-catalyzed Mizoroki-Heck reaction |
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| Authors: | Yuka Kawashita |
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| Institution: | Department of Chemistry, Faculty of Science, Kobe University, Nada, Kobe 657-8501, Japan |
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| Abstract: | A variety of 2-arylbenzothiazoles were prepared by the direct reaction of 2-aminobenzenethiol and aryl aldehydes by the aid of activated carbon (Shirasagi KL or Darco® KB) under oxygen atmosphere. 2-Pyridylbenzothiazole, thus obtained, was proved to work as an efficient ligand in palladium-catalyzed Mizoroki-Heck reaction. |
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