Efficient synthesis of carbohydrate thionolactones |
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| Authors: | Kampanart Chayajarus |
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| Affiliation: | Chemistry Research Laboratory, Oxford University, Mansfield Road, Oxford OX1 3TA, UK |
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| Abstract: | Carbohydrate thionolactones may be efficiently synthesized from the corresponding 1-thio sugars via a two-step procedure involving formation of a glycosyl phenylthiosulfinate by treatment with either phenylsulfinyl chloride or 1-(phenylsulfinyl)piperidine (BSP), and subsequent thermal elimination in toluene. |
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| Keywords: | Carbohydrates 1-Thio sugars Thionolactones Thiosulfinates |
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