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Formal synthesis of fostriecin by a carbohydrate-based approach
Authors:J.S. Yadav  I. Prathap  Bulli Padmaja Tadi
Affiliation:Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:
The formal synthesis of fostriecin starting from d-glucose, involves chelation-controlled addition, Wittig rearrangement, ring closing metathesis and iodomethylenation, as described.
Keywords:d-Glucose   Raney-Ni   Chelation-controlled addition   Wittig rearrangement   Wittig olefination   Chiral allylation   Ring closing metathesis, Iodomethylenation
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