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Synthesis of fused α-methylene-γ-butyrolactone derivatives through pyridine-induced addition of phenols to dimethyl acetylenedicarboxylate
Authors:Issa Yavari  Zinatossadat Hossaini
Affiliation:Chemistry Department, Tarbiat Modarres University, PO Box 14115-175, Tehran, Iran
Abstract:The reaction between dimethyl acetylenedicarboxylate and various phenols including phenol, 1-naphthol, 2-naphthol, 8-hydroxyquinoline, 1,6-dihydroxynaphthalene, cathechol, hydroquinone and resorcinol in the presence of catalytic amounts of pyridine leads to fused α-methylene-γ-butyrolactone derivatives in good yields.
Keywords:Pyridine   Naphthofuran   Naphthol   Acetylenic ester   Butyrolactone   Furanone
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