Stereochemistry of a cubane-like photodimer of methyl 2-naphthoate |
| |
| Authors: | Lei Lei Xiao-Ling Wu Lin Luo Chen-Ho Tung Kui-Ling Ding |
| |
| Affiliation: | a Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100 080, PR China
b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200 032, PR China |
| |
| Abstract: | A novel type of C2-symmetric-chiral ligand, based on a cubane-like photodimer 1 of methyl 2-naphthoate, is reported in this work. Crystal analysis reveals that the methyl carboxylate functionality is in an anti-head-to-head conformation and 1 is highly rigid. The optically pure enantiomers of 1 can be obtained simply by HPLC resolution. |
| |
| Keywords: | Stereochemistry C2-symmetric ligand Cubane-like photodimer Methyl 2-naphthoate |
| 本文献已被 ScienceDirect 等数据库收录！ |
