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Zirconyl nitrate mediated regioselective ring opening of epoxides and aziridines: an easy synthesis of β-nitrato-alcohols and -sulfonamides
Authors:Biswanath Das  Maddeboina Krishnaiah  Katta Venkateswarlu
Institution:Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:Epoxides and aziridines are cleaved efficiently and regioselectively in the presence of zirconyl nitrate at room temperature to afford the corresponding β-nitrato-alcohols and -sulfonamides, respectively, in high yields.
Keywords:Epoxide  Aziridine  Zirconyl nitrate  Ring opening  β-Nitrato-alcohols and -sulfonamides
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