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Aminolysis of allyl esters with bislithium aryl amides
Authors:Catherine A. Faler
Affiliation:Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA
Abstract:The aminolysis of allyl esters with bislithium amides is reported. Tertiary aryl amides were synthesized in a one-pot reaction with bislithium amides and a suitable electrophile in good yields. The scope of this reaction was demonstrated with a variety of anilines and aminopyridines and applied to the synthesis of triphenylmethylacetamides.
Keywords:Aromatic amide   Allyl ester aminolysis   Triphenylmethyl amide
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