Aminolysis of allyl esters with bislithium aryl amides |
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Authors: | Catherine A. Faler |
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Affiliation: | Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA |
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Abstract: | The aminolysis of allyl esters with bislithium amides is reported. Tertiary aryl amides were synthesized in a one-pot reaction with bislithium amides and a suitable electrophile in good yields. The scope of this reaction was demonstrated with a variety of anilines and aminopyridines and applied to the synthesis of triphenylmethylacetamides. |
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Keywords: | Aromatic amide Allyl ester aminolysis Triphenylmethyl amide |
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