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Selective nitrosation of guanazine: preparation of azidoaminotriazole and nitrosoguanazine anion-Cu(II) complexes |
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| Authors: | Magdy Bichay Richard Gilardi Ray J Butcher Michael E Sitzmann Michael D Williams |
| Institution: | a Indian Head Division, Naval Surface Warfare Center, Indian Head, MD 20640, USA b Pacific Scientific Energetic Materials Co., Chandler, AZ 85226, USA c Laboratory for the Structure of Matter, Naval Research Laboratory, Washington, DC 20375, USA d Department of Chemistry, Howard University, Washington, DC 20059, USA |
| Abstract: | Guanazine (3,4,5-triamino-1,2,4-triazole) is selectively nitrosated on C-NH2 to produce nitrosoguanazine (3-nitrosamino-4,5-diamino-1,2,4-triazole). The nitrosoguanazine is used to prepare 5-azido-3-amino-1,2,4-triazole and nitrosoguanazine anion-Cu(II) complexes. |
| Keywords: | Nitrosoguanazine Azidoaminotriazole Nitrosoguanazine anion-Cu(II) complexes |
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