Synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones using iodine monochloride |
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| Authors: | N Suryakiran |
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| Institution: | Organic Chemistry Division-I, Natural Products Laboratory, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | The synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones is described. Reaction of β-ketosulfones with iodine monochloride in acetic acid at room temperature gave the corresponding α-iodo β-ketosulfones, which, on treatment with aqueous alkali, underwent base-induced cleavage to afford α-iodo methylsulfones. |
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| Keywords: | β-Ketosulfones α-Iodo β-ketosulfones α-Iodo methylsulfones |
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