Direct ring functionalisation of 1,4,7-trimethyl-1,4,7-triazacyclononane and its application in the preparation of functional [L2Mn2O3]-type complexes |
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Authors: | Jean H. Koek |
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Affiliation: | Unilever Research Vlaardingen, PO Box 114, 3130 AC Vlaardingen, The Netherlands |
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Abstract: | Treatment of 1,4,7-trimethyl-1,4,7-triazacyclononane (metacn) with N-bromosuccinimide (NBS) gave a bicyclic ammonium intermediate, which was ring-opened to 2-cyano-1,4,7-trimethyl-1,4,7-triazacyclononane by reaction with potassium cyanide. Reduction to the amine followed by reaction with anhydrides gave amides, which could subsequently be converted to dinuclear tris-μ-oxo manganese complexes. |
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Keywords: | N-ligands Manganese Macrocyclic ligands Amines Oxidation Synthetic methods |
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