Indium(I) iodide promoted cleavage of dialkyl/diaryl disulfides and subsequent anti-Markovnikov addition to styrenes: a new route to linear thioethers |
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| Authors: | Brindaban C. Ranu Tanmay Mandal |
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| Affiliation: | Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India |
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| Abstract: | The reaction of thiolate anions, generated in situ by indium(I) iodide promoted cleavage of dialkyl/diaryl disulfides, with styrenes has been investigated. Thiolate anions add to a variety of styrenes in an anti-Markovnikov manner producing linear thioethers in high yields. This method provides a new route to the synthesis of thioethers. |
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| Keywords: | Thioether Anti-Markovnikov addition Styrene Dialkyl disulfide Indium(I) iodide Zinc chloride |
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