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Self-assembled coordination cage derived from small-sized pyridinophane |
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| Authors: | Akihiko Tsuge Ayumi Matsubara Yoshihisa Sei |
| Institution: | a Department of Applied Chemistry, Kyushu Institute of Technology, Tobata-ku, Kitakyushu 804-8550, Japan b Institute of Materials Chemistry and Engineering, Kyushu University, Higashi-ku, Fukuoka 812-8581, Japan c Faculty of Pharmaceutical Science at Kagawa Campus, Tokushima Bunri University, Kagawa 769-2193, Japan |
| Abstract: | The dithia3.3]pyridinophane consisting of two pyridine rings has been found out to assume the syn-structure by the X-ray crystallography, meaning the two nitrogen atoms point in the same direction. From this cyclophane and cis-protected palladium(II), the self-assembled coordination molecular cage has been constructed. |
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