Synthesis of phthalates and isophthalates by [3+3] cyclizations of 1,3-bis(silyl enol ethers) with 3-(silyloxy)alk-2-en-1-ones |
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Authors: | Stefanie Reim Peter Langer |
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Affiliation: | a Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany b Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany |
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Abstract: | 3-Hydroxyphthalates and 4-hydroxyisophthalates were prepared by sequential [3+3] cyclization reactions of 1,3-bis(silyl enol ethers) with 2- and 3-alkoxycarbonyl-3-(silyloxy)alk-2-en-1-ones. |
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Keywords: | Cyclizations Phthalic acid derivatives Silyl enol ethers |
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