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Synthesis of phthalates and isophthalates by [3+3] cyclizations of 1,3-bis(silyl enol ethers) with 3-(silyloxy)alk-2-en-1-ones
Authors:Stefanie Reim  Peter Langer
Institution:a Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany
b Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany
Abstract:3-Hydroxyphthalates and 4-hydroxyisophthalates were prepared by sequential 3+3] cyclization reactions of 1,3-bis(silyl enol ethers) with 2- and 3-alkoxycarbonyl-3-(silyloxy)alk-2-en-1-ones.
Keywords:Cyclizations  Phthalic acid derivatives  Silyl enol ethers
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