Polyoxometalate compound: a highly efficient heterogeneous catalyst for aerobic alcohol oxidation |
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| Authors: | Jianmin Wang Liang Yan Xiaolai Wang |
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| Affiliation: | a State key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b Graduate School of the Chinese Academy of Sciences, 100000, China |
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| Abstract: | Oxidation of alcohols to aldehydes and ketones has been studied using atmospheric oxygen and a catalytic amount of Na6.3Fe0.9[AlMo11O39]·2H2O in toluene under heating (80 or 110 °C) in high yields. Secondary alcohols can be chemoselectively converted into ketones in the presence of primary hydroxyl groups. |
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| Keywords: | Indiscerptible polyoxometalate Oxidation of alcohol Atmospheric oxygen Catalyst separation |
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