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An improved protocol for ligandless Suzuki-Miyaura coupling in water
Authors:Dmitrii N. Korolev
Affiliation:Lomonosov MSU, Department of Chemistry, 119992, GSP-2, Moscow, Leninskie Gori, Russian Federation
Abstract:Using a reverse order of addition of reagents, PdCl2 and Pd(OAc)2 are efficient catalysts for the Suzuki-Miyaura reactions in water. The ligandless and mild conditions, the high stability of the catalytic system, short reaction time and good to excellent yields are important features of this protocol.
Keywords:Suzuki-Miyaura reaction   Ligandless palladium   Biaryls   Catalysis
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