Dichlorocarbene adducts of alkyl enol ethers as precursors to furans: application to a total synthesis of the furanosesquiterpene (±)-pallescensin A |
| |
| Authors: | Jonathan S. Foot |
| |
| Affiliation: | Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, ACT 0200, Australia |
| |
| Abstract: | A novel method for annulating furans to ketones, involving treatment of the dichlorocarbene adduct of the derived methyl enol ether with base, has been exploited in the synthesis of the title natural product 1 from the known trans-decalone 2. |
| |
| Keywords: | Cyclopropene Dichlorocyclopropane Furan Furanosesquiterpene Pallescensin A Wieland-Miescher ketone |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
