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Grubbs catalyst-mediated cycloisomerization of allenenes
Authors:Chisato Mukai  Rumiko Itoh
Affiliation:Division of Pharmaceutical Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan
Abstract:The novel ruthenium benzylidene catalyst-mediated cycloisomerization of allenenes, having an alkyl appendage at the allenic terminus, resulting in the construction of cyclohexene, tetrahydropyran, and tetrahydropyridine skeletons was developed.
Keywords:Grubbs catalyst   Cycloisomerization   Allenene   Ring-closing reaction
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